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(S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL CAS NO.100165-88-6
- Min.Order: 1 Gram
- Payment Terms: T/T,Other
- Product Details
Keywords
- (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
- 100165-88-6
- 99%purity
Quick Details
- ProName: (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-...
- CasNo: 100165-88-6
- Molecular Formula: C48 H40 P2
- Appearance: White powder
- Application: intermediate
- DeliveryTime: instock
- PackAge: according to the need of packing
- Port: Shanghai
- ProductionCapacity: 100 Kilogram/Day
- Purity: 98%
- Storage: dry, low temperature
- Transportation: air sea or courier
- LimitNum: 1 Gram
Superiority
Product Name: (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
CAS: 100165-88-6
MF: C48 H40 P2
MW: 678.78
EINECS: 1312995-182-4
Melting point 252-256 °C
alpha -160° (c 0.5, C6H6)
Boiling point 754.4±60.0 °C(Predicted)
form Powder
color White
optical activity [α]20/D -156°, c = 0.5 in benzene
Water Solubility Insoluble in water.
InChIKey IOPQYDKQISFMJI-UHFFFAOYSA-N
Reaction
Useful ligand for palladium-catalyzed carbon-oxygen bond formation.
Ligand for palladium-catalyzed α-arylation of ketones.
Ligand for Cu-catalyzed asymmetric conjugate reduction.
Ligand for Cu-catalyzed asymmetric dienolate addition to aldehydes.
Enantioselective conjugate reduction of lactones and lactams.
Ligand used in the enantioselective cycloaddition of allenylsilanes with α-Imino esters.
Catalytic Aldol reaction to ketones.
Ligand with rhodium catalyses [2+2+2] cycloaddition reaction of alkenes and alkynes.
Ligand used in the iridium-catalyzed enantioselective C-H bond activation of 2-(alkylamino)-pyridine with alkenes.
Iridium-catalyzed regio-, diastereo-, and enantioselective tert-(hydroxyl)-prenylation of alcohols.
Rhodium-catalyzed cross cyclotrimerization.
Details
Product Name: (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL
CAS: 100165-88-6
MF: C48 H40 P2
MW: 678.78
EINECS: 1312995-182-4
Melting point 252-256 °C
alpha -160° (c 0.5, C6H6)
Boiling point 754.4±60.0 °C(Predicted)
form Powder
color White
optical activity [α]20/D -156°, c = 0.5 in benzene
Water Solubility Insoluble in water.
InChIKey IOPQYDKQISFMJI-UHFFFAOYSA-N
Reaction
Useful ligand for palladium-catalyzed carbon-oxygen bond formation.
Ligand for palladium-catalyzed α-arylation of ketones.
Ligand for Cu-catalyzed asymmetric conjugate reduction.
Ligand for Cu-catalyzed asymmetric dienolate addition to aldehydes.
Enantioselective conjugate reduction of lactones and lactams.
Ligand used in the enantioselective cycloaddition of allenylsilanes with α-Imino esters.
Catalytic Aldol reaction to ketones.
Ligand with rhodium catalyses [2+2+2] cycloaddition reaction of alkenes and alkynes.
Ligand used in the iridium-catalyzed enantioselective C-H bond activation of 2-(alkylamino)-pyridine with alkenes.
Iridium-catalyzed regio-, diastereo-, and enantioselective tert-(hydroxyl)-prenylation of alcohols.
Rhodium-catalyzed cross cyclotrimerization.