Trioctylamine 1116-76-3 Large in supply CAS NO.1116-76-3

Synonyms: TNOA;TRICAPRYLYLAMINE;TRICAPRYLAMINE;TRI-N-OCTYLAMINE;TRIOCTYLAMINE;1-Octanamine,N,N-dioctyl-;336S;Alamine 308
CAS: 1116-76-3
MF: C24H51N
MW: 353.67
EINECS: 214-242-1
Product Categories: Organics;Amines;C11 to C38;Nitrogen Compounds;C17 to C40+;Building Blocks;Chemical Synthesis;Nitrogen Compounds;Organic Building Blocks;Basic organic chemicals;solvent;Isoquinolines ,Quinolines ,Quinaldines
Mol File: 1116-76-3.mol
Tri-n-octylamine Structure
Tri-n-octylamine Chemical Properties
Melting point  34 °C
Boiling point  164-168 °C0.7 mm Hg(lit.)
density  0.810 g/mL at 20 °C
refractive index  n20/D 1.449(lit.)
Fp  >230 °F
storage temp.  Store below +30°C.
solubility  chloroform: 0.1 g/mL, clear, colorless
Water Solubility  Miscible with chloroform. Immiscible with water.
Sensitive  Air Sensitive
BRN  1210618
CAS DataBase Reference 1116-76-3(CAS DataBase Reference)
NIST Chemistry Reference 1-Octanamine, N,N-dioctyl-(1116-76-3)
EPA Substance Registry System 1-Octanamine, N,N-dioctyl-(1116-76-3)
Safety Information
Hazard Codes  Xi,N
Risk Statements  36/37/38-51/53
Safety Statements  26-61-36/37/39-29
RIDADR  UN3082
WGK Germany  2
RTECS  RG8225000
F  10-23
TSCA  Yes
HazardClass  9
PackingGroup  III
HS Code  29211980
Hazardous Substances Data 1116-76-3(Hazardous Substances Data)

Synonyms】

N,N-Dioctyloctan-1-amine
Tri-n-octylamine
【CAS】

1116-76-3
【Formula】

C24H51N
【Molecular Weight】

353.68
【EINECS】

214-242-1
【RTECS】

RG8225000
【RTECS Class】

Other
【Beilstein/Gmelin】

1210618
【Beilstein Reference】

4-11-00-00122
【EC Class】

irritant, dangerous for the environment
Physical and Chemical Properties Back to Contents
【Appearance】

Clear, colorless liquid.
【Solubility in water】

Insoluble.
【Melting Point】

-39
【Boiling Point】

365
【Vapor Pressure】

0.075 (20 C)
【Density】

0.812 g/cm3
【pKa/pKb】

3.92 (pKb)
【Partition Coefficient】

11.22
【Heat Of Vaporization】

61.0 kJ/mol
【Heat Of Combustion】

-16145 kJ/mol
【Usage】

Component of defoliant formulation.
【Vapor Density】

12.1
【Refractive Index】

1.4509
First Aid Measures Back to Contents
【Ingestion】

Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
【Inhalation】

Remove from exposure to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. DO NOT use mouth-to-mouth respiration. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】

Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Handling and Storage Back to Contents
【Storage】

Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
【Handling】

Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Wash clothing before reuse.
Hazards Identification Back to Contents
【Inhalation】

Causes respiratory tract irritation. May cause methemoglobinemia, cyanosis, convulsions, tachycardia, dyspnea, and death. May cause liver and kidney damage. May cause cardiac abnormalities. Can produce delayed pulmonary edema. Inhalation at high concentrations may cause CNS depression and asphixiation.
【Skin】

Causes skin irritation. May cause severe irritation and possible burns.
【Eyes】

Causes eye irritation. May cause chemical conjunctivitis.
【Ingestion】

May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause liver and kidney damage. May cause cardiac disturbances. May cause methemoglobinemia, cyanosis, convulsions, and death. May cause central nervous system depression.
【Hazards】

When heated, vapors may form explosive mixtures with air: indoors, outdoors, and sewers explosion hazards.
【EC Risk Phrase】

R 36/38
【EC Safety Phrase】

S 26 36
【UN (DOT)】

2735
Exposure Controls/Personal Protection Back to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
【Exposure Effects】

May cause liver and kidney damage. May cause methemoglobinemia, which is characterized by chocolate-brown colored blood, headache, weakness, dizziness, breath shortness, cyanosis, rapid heart rate, unconsciousness and possible death. Effects may be delayed.
【Poison Class】

3
Fire Fighting Measures Back to Contents
【Flash Point】

147
【Autoignition】

315
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Containers may explode when heated. Combustible material; may burn but does not ignite readily. Runoff from fire control or dilution water may cause pollution. Extinguishing media: Use water spray to cool fire-exposed containers. Do NOT get water inside containers. For small fires, use dry chemical, carbon dioxide, or water spray. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray.
【Fire Potential】

Combustible material: may burn but does not ignite readily.
Accidental Release Measures Back to Contents
【Small spills/leaks】

Absorb spill with inert material, (e.g., dry sand or earth), then place into a chemical waste container. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, using the appropriate protective equipment. Provide ventilation.
Stability and Reactivity Back to Contents
【Disposal Code】

5
【Incompatibilities】

Oxidizing agents, acids, acid anhydrides, acid chlorides, chloroformates.
【Stability】

Stable at room temperature in closed containers under normal storage and handling conditions.
【Decomposition】

Nitrogen oxides, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, nitrogen.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport Information Back to Contents
【UN Number】

2735
【Hazard Class】

8
【Packing Group】

I; II; III
【HS Code】

2921 19 80