(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) CAS NO.138517-61-0

Product Name:    (1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL)
Synonyms:    (1R, 2R) - (+) - 1,2- hexanediaMine -N, N'- diphenyl-phosphine-benzoyl;Benzamide, N,N'-(1R,2R)-1,2-cyclohexanediylbis[2-(diphenylphosphino)-;N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphi no)benzamide],99%e.e.;N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphi no)benzamide];TROST LIGAND;(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL);(1R,2R)-(+)-1,2-TROST LIGAND;"N,N'-(1R,2R)-1,2-Cyclohexanediylbis[2-(diphenylphosphino)benzamide]/ (R,R)-DACH-phenyl Trost ligand"
CAS:    138517-61-0
MF:    C44H40N2O2P2
MW:    690.75               
Mol File:    138517-61-0.mol

Melting point     134-136°C
alpha     +130° (c 1.0, methanol)
Boiling point     817.0±65.0 °C(Predicted)
storage temp.     Inert atmosphere,2-8°C
form     Powder
pka    13.35±0.40(Predicted)
color     white to off-white
optical activity    [α]20/D +131°, c = 1 in methanol
Safety Information
Risk Statements     36/37/38
Safety Statements     26-36/37/39
WGK Germany     3
MSDS Information
(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Usage And Synthesis
Reaction    The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen, oxygen, sulfur, and fluorides nucleophiles. 

(1R,2R)-(+)-1,2-DIAMINOCYCLOHEXANE-N,N'-BIS(2'-DIPHENYLPHOSPHINOBENZOYL) Preparation Products And Raw materials