2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos CAS NO.1070663-78-3

Product Name:    2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos
Synonyms:    2-(Dicyclohexylphosphino)-3,6-diMethoxy-2'-4' -6'-tri-i-propyl-1,1'-biphenyl;2-Dicyclohexylphosphino-2',4',6'-triisopropyl-3,6-diMethoxybiphenyl, 97+%;2-Dicyclohexylphosphino-2',4',6'-tri-i-propyl-3,6-diMethoxy-1,1'-biphenyl, 98% (BrettPhos);BrettPhos 96%;2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos;2-(Dicyclohexylphosphino)3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl;BRETTPHOS;Dicyclohexyl(2',4',6'-triisopropyl-3,6-diMethoxy-[1,1'-biphenyl]-2-yl)phosphine
CAS:    1070663-78-3
MF:    C35H53O2P
MW:    536.77
EINECS:    
Product Categories:    Achiral Phosphine;Aryl Phosphine;Buchwald Ligands Series;Buchwald Ligands&Precatalysts
Mol File:    1070663-78-3.mol
Melting point     191-193℃
Boiling point     607.7±55.0 °C(Predicted)
form     crystal
color     white
InChIKey    WDVGNXKCFBOKDF-UHFFFAOYSA-N
Safety Information
Risk Statements     36/37/38
Safety Statements     26-37-60
WGK Germany     nwg
TSCA     No
MSDS Information
2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos Usage And Synthesis
Reactions    
Ligand for palladium-catalyzed cross-coupling reactions using aryl mesylates with electron-deficient anilines.
Ligand for palladium-catalyzed cross-coupling of primary arylamines at low catalyst loading.
Ligand for palladium-catalyzed cross-coupling of aryl iodides and primary amines.
Ligand for the Suziki-Miyaura coupling of tosylates and mesylates.
Ligand for the palladium-catalyzed trifluoromethylation of aryl chlorides.
Ligand for the palladium-catalyzed formation of aryl-SCF3 compounds from aryl bromides.
Ligand for the nickel-catalyzed cross-coupling of styrenyl epoxides with boronic acids.
Ligand for the palladium-catalyzed intramolecular CH difluoroalkylation.

Uses    Ligand for the Suziki-Miyaura coupling of tosylates and mesylates.

Product Name:    2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos
Synonyms:    2-(Dicyclohexylphosphino)-3,6-diMethoxy-2'-4' -6'-tri-i-propyl-1,1'-biphenyl;2-Dicyclohexylphosphino-2',4',6'-triisopropyl-3,6-diMethoxybiphenyl, 97+%;2-Dicyclohexylphosphino-2',4',6'-tri-i-propyl-3,6-diMethoxy-1,1'-biphenyl, 98% (BrettPhos);BrettPhos 96%;2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos;2-(Dicyclohexylphosphino)3,6-dimethoxy-2′,4′,6′-triisopropyl-1,1′-biphenyl;BRETTPHOS;Dicyclohexyl(2',4',6'-triisopropyl-3,6-diMethoxy-[1,1'-biphenyl]-2-yl)phosphine
CAS:    1070663-78-3
MF:    C35H53O2P
MW:    536.77
EINECS:    
Product Categories:    Achiral Phosphine;Aryl Phosphine;Buchwald Ligands Series;Buchwald Ligands&Precatalysts
Mol File:    1070663-78-3.mol
Melting point     191-193℃
Boiling point     607.7±55.0 °C(Predicted)
form     crystal
color     white
InChIKey    WDVGNXKCFBOKDF-UHFFFAOYSA-N
Safety Information
Risk Statements     36/37/38
Safety Statements     26-37-60
WGK Germany     nwg
TSCA     No
MSDS Information
2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos Usage And Synthesis
Reactions    
Ligand for palladium-catalyzed cross-coupling reactions using aryl mesylates with electron-deficient anilines.
Ligand for palladium-catalyzed cross-coupling of primary arylamines at low catalyst loading.
Ligand for palladium-catalyzed cross-coupling of aryl iodides and primary amines.
Ligand for the Suziki-Miyaura coupling of tosylates and mesylates.
Ligand for the palladium-catalyzed trifluoromethylation of aryl chlorides.
Ligand for the palladium-catalyzed formation of aryl-SCF3 compounds from aryl bromides.
Ligand for the nickel-catalyzed cross-coupling of styrenyl epoxides with boronic acids.
Ligand for the palladium-catalyzed intramolecular CH difluoroalkylation.

Uses    Ligand for the Suziki-Miyaura coupling of tosylates and mesylates.