Lithium perchlorate trihydrate 13453-78-6 CAS NO.13453-78-6

Synonyms: LITHIUM PERCHLORATE HYDRATE;LITHIUM PERCHLORATE TRIHYDRATE;Lithium perchlorate trihydrate, extra pure, 99+%;LITHIUM PERCHLORATE, TRIHYDRATE (ACS) REAGENT;Lithiumperchloratetrihydrate,98%;Perchloric acid, lithium salt, trihydrate;lithium perchlorate trihydrate, reagent grade;Lithium pechlorate trihydrate
CAS: 13453-78-6
MF: ClH6LiO7
MW: 160.44
EINECS: 232-237-2
Product Categories: Oxidation;Perchlorates;Synthetic Reagents;metal perchlorate salt
Mol File: 13453-78-6.mol
Lithium perchlorate trihydrate Structure
Lithium perchlorate trihydrate Chemical Properties
Melting point  95 °C
density  1.841 g/mL at 25 °C(lit.)
Water Solubility  597 g/L (25 ºC)
Sensitive  Hygroscopic
Merck  14,5539
CAS DataBase Reference 13453-78-6(CAS DataBase Reference)
Safety Information
Hazard Codes  O,Xi
Risk Statements  8-36/37/38
Safety Statements  17-26-27-36/37/39-37/39
RIDADR  UN 1481 5.1/PG 2
WGK Germany  1
RTECS  SC8750000
TSCA  Yes
HazardClass  5.1
PackingGroup  II

【CAS】

13453-78-6
【Formula】

ClO4.3H2O.Li
【Formula】

LiClO4.3H2O
【Molecular Weight】

160.44
【RTECS】

SC8750000
【RTECS Class】

Other
【Beilstein/Gmelin】

22527 (G)
Physical and Chemical Properties Back to Contents
【Appearance】

White crystalline powder.
【Melting Point】

91.85
【Density】

1.841 g/cm3
【Usage】

A source of oxygen in some chemical oxygen generators. An electrolyte in lithium batteries.
First Aid Measures Back to Contents
【Ingestion】

If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
【Inhalation】

Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
【Skin】

Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
【Eyes】

Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Handling and Storage Back to Contents
【Storage】

Keep away from heat, sparks, and flame. Do not store near combustible materials. Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed.
【Handling】

Wash thoroughly after handling. Use only in a well ventilated area. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Avoid contact with clothing and other combustible materials. Avoid ingestion and inhalation.
Hazards Identification Back to Contents
【Ingestion】

May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
【Inhalation】

May cause respiratory tract irritation.
【Skin】

May cause skin irritation.
【Eyes】

May cause eye irritation.
【Hazards】

May explode from heat or contamination. May react explosively with hydrocarbons (fuels). May ignite combustibles.
【UN (DOT)】

1481
Exposure Controls/Personal Protection Back to Contents
【Personal Protection】

Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.
【Respirators】

Follow the OSHA respirator regulations found in 29CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.
Fire Fighting Measures Back to Contents
【Fire Fighting】

Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with combustible materials may cause a fire. Use water with caution and in flooding amounts. Extinguishing media: Use water only! Contact professional fire-fighters immediately.
【Fire Potential】

These substances will accelerate burning when involved in a fire.
Accidental Release Measures Back to Contents
【Small spills/leaks】

Clean up spills immediately, using the appropriate protective equipment. Avoid generating dusty conditions. Remove all sources of ignition. Provide ventilation. In case of spill, sweep up solid or absorb liquid with inert material, then place into a biohazard container. Wear protective equipment.
Stability and Reactivity Back to Contents
【Stability】

Stable under normal temperatures and pressures.
【Incompatibilities】

Strong reducing agents, acetone, nitromethane, platinum, oxygen, hydrogen.
【Decomposition】

Chlorine, irritating and toxic fumes and gases, lithium oxides.
【Combustion Products】

Fire may produce irritating, corrosive and/or toxic gases.
Transport Information Back to Contents
【UN Number】

1481
【Hazard Class】

5.1
【Packing Group】

II; III